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Beilstein J. Org. Chem. 2007, 3, No. 9, doi:10.1186/1860-5397-3-9
Graphical Abstract
Figure 1: Cyclic and acyclic sterically encumbered silanes.
Scheme 1: Cyclic and acyclic chiral silanes as potent reagents for the silicon-to-carbon chirality transfer.
Scheme 2: Kinetic resolution of secondary alcohols using a dehydrogenative coupling reaction.
Scheme 3: Catalytic cycle for hydrosilylation.
Scheme 4: Postulated catalytic cycle for dehydrogenative coupling.